Breakthrough discovery skyrockets hydrogen production by over 1000% using common metal

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Written By Alicia Green

Scientific writer

New hope for more sustainable hydrogen.

the RIKEN Center for Sustainable Resource Science in Japan announced a significant breakthrough that could redefine the future of hydrogen energy. Their discovery in hydrogen extraction from water signifies the dawn of a new era for the hydrogen-based energy economy, potentially setting the stage for a revolution in sustainable energy production.

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A giant leap in water electrolysis

Led by Ryuhei Nakamura, the research team has developed a revolutionary process that enhances the extraction of hydrogen from water using a bespoke catalyst. By manipulating the 3D structure of the catalyst, they have not only improved its stability but also dramatically extended its lifespan. This breakthrough is poised to play a pivotal role in establishing a sustainable hydrogen-centric energy economy.

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Overcoming the challenge of rare metals

Traditional water electrolysis relies on rare metals like iridium, which are used in highly acidic environments. Nakamura pointed out that scaling up proton exchange membrane (PEM) electrolysis to terawatt levels would require an iridium amount equivalent to 40 years of current productionโ€”a scenario that is both impractical and unsustainable. In response, his team has innovated a rare-metal-free acidic water electrolysis process using an abundantly available catalyst.

The manganese oxide breakthrough

The team’s innovation centers around a modified form of manganese oxide (MnO2), designed to increase the stability of the reaction. The manganese oxide features a 3D lattice structure with oxygen in two configurations: planar and pyramidal. By increasing the planar oxygen content, researchers significantly boosted catalytic stability, marking a major advance in the field.

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Promising tests and results

Experiments with various forms of manganese oxides showed that the version with the highest planar oxygen content (94%) maintained the oxygen evolution reaction in acid for a month at 1000 mA/cmยฒ. This represents a charge transfer amount 100 times greater than that observed in previous studies.

Efficiency and application potential

During trials in a PEM electrolyzer, water electrolysis was sustained for about six weeks at 200 mA/cmยฒ, producing ten times more hydrogen than other non-rare metallic catalysts. This improved stability did not come at the cost of reduced activity, which is often the case. This represents a remarkable efficiency for a PEM electrolyzer using an earth-abundant catalyst.

Towards a sustainable future

While more work is needed to achieve industrial-scale applications, researchers are optimistic about the potential of their findings to contribute to carbon neutrality. Future modifications to the catalyst’s structure could further increase both current density and catalyst lifespan, aiming in the long term to enable iridium-free PEM water electrolysis.

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This article explores the recent breakthrough in sustainable hydrogen production at the RIKEN Center for Sustainable Resource Science. The manipulation of the 3D structure of a manganese-based catalyst has led to a significant increase in stability and lifespan, opening up promising prospects for a hydrogen-based energy economy. With its implications for water electrolysis and rare-metal-free hydrogen production, this advancement marks a potential turning point toward a greener, more accessible energy source.

Source : Nature